Uranosena: Perbedaan antara revisi
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'''Uranocene''', U(C<sub>8</sub>H<sub>8</sub>)<sub>2</sub>, adalah [[senyawa organouranium]] yang tersusun dari atom uranium yang diapit diantara dua cincin [[Siklooktatetraena|siklooktatetraenida]]. Senyawa tersebut adalah salah satu [[senyawa organoaktinida]] pertama yang disintesis. Senyawa tersebut adalah padatan hijau yang sensitif terhadap udara yang larut dalam pelarut organik. Uranosena, salah satu anggota dari "[[aktinosena]]," sekelompok [[metalosena]] yang menggabungkan [[Unsur|unsur-unsur]] dari rangkaian [[aktinida]].<ref name=Seyferth>{{cite journal |last= Seyferth |first= D. |title= Uranocene. The First Member of a New Class of Organometallic Derivatives of the f Elements |year= 2004 |journal= [[Organometallics]] |volume= 23 |issue= 15 |pages= 3562–3583 |doi= 10.1021/om0400705|doi-access= free}}</ref><ref>{{Cite journal|last1=Zalkin|first1=Allan|last2=Raymond|first2=Kenneth N.|date=1969|title=Structure of di-.pi.-cyclooctatetraeneuranium (uranocene)|url=https://pubs.acs.org/doi/abs/10.1021/ja01048a055|journal=Journal of the American Chemical Society|language=en|volume=91|issue=20|pages=5667–5668|doi=10.1021/ja01048a055|issn=0002-7863}}</ref><ref>{{cite journal |last1= Clark |first1= J. P. |last2= Green |first2= J. C. |title= An Investigation of the Electronic Structure of Bis(''eta''-cyclo-octatetraene)-actinoids by Helium-(I) and -(II) Photoelectron Spectroscopy |year= 1977 |journal= [[J. Chem. Soc., Dalton Trans.]] |issue= 5 |pages= 505–508 |doi= 10.1039/DT9770000505}}</ref><ref>{{cite journal |last1= Roesch |first1= N. |last2= Streitwieser |first2= A. |title= Quasirelativistic SCF-X''alpha'' Scattered-Wave Study of Uranocene, Thorocene, and Cerocene |year= 1983 |journal= [[J. Am. Chem. Soc.]] |volume= 105 |issue= 25 |pages= 7237–7240 |doi= 10.1021/ja00363a004}}</ref><ref name=chang>{{cite journal |last1= Chang |first1= A. H. H. |last2= Pitzer |first2= R. M. |title= Electronic Structure and Spectra of Uranocene |year= 1989 |journal= [[J. Am. Chem. Soc.]] |volume= 111 |issue= 7 |pages= 2500–2507 |doi= 10.1021/ja00189a022}}</ref><ref>{{cite journal |last1= Karraker |first1= D. G. |last2= Stone |first2= J. A. |last3= Jones |first3= E. R. |last4= Edelstein |first4= N. |title= Bis(cyclooctatetraenyl)neptunium(IV) and Bis(cyclooctatetraenyl)plutonium(IV) |year= 1970 |journal= [[J. Chem. Phys.]] |volume= 92 |issue= 16 |pages= 4841–4845 |doi= 10.1021/ja00719a014}}</ref><ref>{{cite book |last= Fischer |first= R. D. |editor1-last= Marks |editor1-first= T. J. |editor2-last= Fischer |editor2-first= R. D. |title= Volume 44 – Organometallics of the f-Elements |series= NATO Advanced Study Institutes Series: Series C – Mathematical and Physical Sciences |publisher= Reidel |location= Dordrecht, Holland |year= 1979 |pages= 337–377 |chapter= NMR Spectroscopy of Organometallic Compounds of the f-Elements: Practical Applications |isbn= 90-277-0990-4}}</ref><ref>{{cite journal |last1= Hayes |first1= R. G. |last2= Edelstein |first2= N. |title= An Elementary Molecular Orbital Calculation on U(C<sub>8</sub>H<sub>8</sub>)<sub>2</sub> and Its Application to the Electronic Structure of U(C<sub>8</sub>H<sub>8</sub>)<sub>2</sub>, Np(C<sub>8</sub>H<sub>8</sub>)<sub>2</sub>. and Pu(C<sub>8</sub>H<sub>8</sub>)<sub>2</sub> |year= 1972 |journal= J. Am. Chem. Soc. |volume= 94 |issue= 25 |pages= 8688–8691 |doi= 10.1021/ja00780a008}}</ref><ref>{{cite journal |last1= Liu |first1= W. |last2= Dolg |first2= M. |last3= Fulde |first3= P. |year= 1997 |title= Low-lying electronic states of lanthanocenes and actinocenes M(C<sub>8</sub>H<sub>8</sub>)<sub>2</sub> (M=Nd, Tb, Yb, U) |journal= [[J. Chem. Phys.]] |volume= 107 |issue= 9 |pages= 3584–3591 |doi= 10.1063/1.474698|bibcode= 1997JChPh.107.3584L }}</ref><ref>{{cite book |last= Herzberg |first= G. |title= Molecular Spectra and Molecular Structure III. Electronic Spectra and Electronic Structure of Polyatomic Molecules |year= 1966 |publisher= D. Van Nostrand |location= Princeton, New Jersey |page= 566}}</ref><ref name=dall>{{cite journal |last1= Dallinger |first1= R. F. |last2= Stein |first2= P. |last3= Spiro |first3= T. G. |title= Resonance Raman Spectroscopy of Uranocene: Observation of an Anomalously Polarized Electronic Band and Assignment of Energy Levels |year= 1978 |journal= [[J. Am. Chem. Soc.]] |volume= 100 |issue= 25 |pages= 7865–7870 |doi= 10.1021/ja00493a013}}</ref><ref>{{cite journal |last1= Hager |first1= J. S. |last2= Zahardis |first2= J. |last3= Pagni |first3= R. M. |last4= Compton |first4= R. N. |last5= Li |first5= J. |display-authors= 3 |title= Raman under nitrogen. The high-resolution Raman spectroscopy of crystalline uranocene, thorocene, and ferrocene |year= 2004 |journal= [[J. Chem. Phys.]] |volume= 120 |issue= 6 |pages= 2708–2718 |doi= 10.1063/1.1637586 |pmid= 15268415|bibcode= 2004JChPh.120.2708H }}</ref>
:[[File:Uranocene synthesis.svg|550px|Synthesis of uranocene]]
== Referensi ==
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{{Kimia-stub}}
[[Kategori:Metalosena]]
[[Kategori:Senyawa organouranium]]
[[Kategori:Senyawa uranium(IV)]]
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