Mangan(III) fluorida: Perbedaan antara revisi

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Revisi per 11 Januari 2023 02.42 sunting Ahmad Alkimya (bicara \| kontrib) 129 suntingan ←Membuat halaman berisi '{{chembox \| Verifiedfields = changed \| Watchedfields = changed \| verifiedrevid = 441473780 \| Name = Mangan(III) fluorida \| ImageFile =MnF3structure.jpg \| ImageName = Mangan(III) fluorida \| IUPACName = Manganese(III) fluoride \| OtherNames = Mangan trifluorida, manganit fluorida \|Section1={{Chembox Identifiers \| ChemSpiderID_Ref = {{chemspidercite\|correct\|chemspider}} \| ChemSpiderID = 74193 \| EINECS = 232-006-6 \| InChI = 1/3FH.Mn/h3*1H;/q;;;+3/p-3 \| InChIKey = SRVI...'		Revisi terkini sejak 24 November 2023 06.36 sunting balikkan Beatrixliezy (bicara \| kontrib) 125 suntingan Fitur saranan suntingan: 2 pranala ditambahkan. Tag: VisualEditor Tugas pengguna baru Disarankan: tambahkan pranala
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Baris 4: \| verifiedrevid = 441473780 \| Name = Mangan(III) fluorida \| ImageFile =~~MnF3structure~~ Manganese-trifluoride-from-xtal-unit-cell-3D-bs-17.~~jpg~~png \| ImageName = Mangan(III) fluorida \| IUPACName = Manganese(III) fluoride Baris 45: \| MainHazards = uap beracun \| GHSPictograms = {{GHS03}}{{GHS06}} \| GHSSignalWord = ~~danger~~Berbahaya \| HPhrases = {{~~HPhrases~~H-phrases\|272\|301\|312\|315\|319\|332\|335}} \| PPhrases = {{~~PPhrases~~P-phrases\|220\|261\|280\|301+310\|305+351+338}} \| GHS_ref = <ref>GHS: [https://www.sigmaaldrich.com/catalog/product/ALDRICH/339296 sigma-aldrich 339296] {{Dead link\|date=December 2021}}</ref> }} Baris 60: ==Sintesis, struktur, dan reaksi== MnF<sub>3</sub> dapat dibuat dengan mereaksikan larutan MnF<sub>2</sub> dalam hidrogen fluorida dengan [[fluor]]: <ref name="mad">{{cite journal \| title = Room temperature syntheses of MnF<sub>3</sub>, MnF<sub>4</sub> and hexafluoromanganete(IV) salts of alkali cations \| author = Z. Mazej Baris 72: :MnF<sub>2</sub> + 0.5 F<sub>2</sub> → MnF<sub>3</sub> Ini juga dapat dibuat dengan mereaksikan unsur fluorin dengan mangan(II) halida pada ~250  °C.<ref name="shap">Inorganic chemistry, Catherine E. Housecroft, A.G. Sharpe, pp.711-712, section ''Manganese (III)'' , [https://books.google.com/books?id=3sy4ZAP4EGAC&dq googlebooks link]</ref> ===Struktur=== Baris 85: </ref> Hidrat MnF<sub>3</sub><sup>.</sup>3H<sub>2</sub>O diperoleh dengan [[kristalisasi]] MnF<sub>3</sub> dari [[asam fluorida]]. Hidrat tersedia sebagai dua polimorf, dengan grup ruang P2<sub>1</sub>/c dan P2<sub>1</sub>/a. Masing-masing terdiri dari garam Mn(H<sub>2</sub>O)<sub>4</sub>F<sub>2</sub>]<sup>+</sup>[Mn(H<sub>2</sub>O)<sub>2</sub>F<sub>4</sub>]<sup>−</sup> ).<ref>{{cite journal \|author1=Molinier Michel \|author2=Massa Werner \| year = 1992 \| title = Structures of two polymorphs of MnF3·3H2O \| journal = Journal of Fluorine Chemistry \| volume = 57 \| issue = 1–3\| pages = 139–146 \| doi=10.1016/S0022-1139(00)82825-0}}</ref> ===Reaksi=== MnF<sub>3</sub> bersifat [[asam Lewis]] dan membentuk berbagai turunan. Salah satu contohnya adalah K<sub>2</sub>MnF<sub>3</sub>(SO<sub>4</sub>).<ref>{{cite book \|author1=Bhattacharjee, M. N \|author2=Chaudhuri, M. K. \| title = Dipotassium Trifluorosulfatomanganate(III) \| journal = [[Inorg. Synth.]] \| year = 1990 \| volume = 27 \| pages = 312–313 \| doi = 10.1002/9780470132586.ch61\|series=Inorganic Syntheses \|isbn=9780470132586 }}</ref> MnF<sub>3</sub> bereaksi dengan [[natrium fluorida]] menghasilkan heksafluorida oktahedral: <ref name="shap"/> :3NaF + MnF<sub>3</sub> → Na<sub>3</sub>MnF<sub>6</sub> Reaksi terkait garam dari anion MnF<sub>5</sub><sup>2−</sup> atau MnF<sub>4</sub><sup>−</sup>. Anion ini masing-masing mengadopsi struktur rantai dan lapisan, dengan menjembatani fluorida. Mangan tetap 6 koordinat, oktahedral, dan trivalen di semua bahan ini.<ref name="shap"/> Mangan(III) fluorida memfluorinasi senyawa organik termasuk [[hidrokarbon aromatik]],<ref>[http://notes.fluorine1.ru/contents/Nov98/Notes/letters/letter1.html Fluorination of p-chlorobenzotrifluoride by manganese trifluoride] {{webarchive\|url=https://web.archive.org/web/20110823102228/http://notes.fluorine1.ru/contents/Nov98/Notes/letters/letter1.html \|date=2011-08-23 }} A. Kachanov, V. Kornilov, V.Belogay , Fluorine Notes :Vol. 1 (1) November–December 1998 , via ''notes.fluorine1.ru''</ref> [[siklobutena]],<ref>{{cite journal\|title=Fluorination of Fluoro-Cyclobutene with High-Valency Metal Fluoride\|authors= Junji Mizukado, Yasuhisa Matsukawa, Heng-dao Quan, Masanori Tamura, Akira Sekiya\|journal=Journal of Fluorine Chemistry\|volume=127\|year=2006\|pages=79–84\|doi=10.1016/j.jfluchem.2005.10.007}}</ref> dan [[fullerena]].<ref>{{cite journal\|title=Fluorination of the Cubic and Hexagonal C<sub>60</sub> Modifications by Crystalline Manganese Trifluoride\|journal=Physics of the Solid State\|volume=44\|issue=4\|year=2002\|pages=629–630\|authors=V. É. Aleshina, A. Ya. Borshchevskii, E. V. Skokan, I. V. Arkhangel'skii, A.V. Astakhov, N.B. Shustova\|doi=10.1134/1.1470543\|bibcode=2002PhSS...44..629A\|s2cid=94250136}}</ref> Saat pemanasan, MnF<sub>3</sub> terurai menjadi [[mangan(II) fluorida]].<ref>{{cite EB1911\|\|wstitle=Manganese#Manganic Salts \|display=Manganese § Manganic Salts \|volume=17 \|page=570}}</ref><ref>In situ time-resolved X-ray diffraction study of manganese trifluoride thermal decomposition , J.V. Raua, V. Rossi Albertinib, N.S. Chilingarova, S. Colonnab, U. Anselmi Tamburini, Journal of Fluorine Chemistry 4506 (2001) 1–4 , [http://ftp.esrf.eu/pub/UserReports/21876_A.pdf online version]</ref> Baris 101: ==Referensi== {{Reflist}} {{Senyawa mangan}} {{Senyawa fluorin}} [[Kategori:Fluorida]] [[Kategori:Senyawa mangan(III)\|Fluorida]]