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{{distinguish|Florin|Fluorida|Fluorena|Fluoron}}
{{Kotak info fluorin}}
Di antara semua unsur, fluorin menempati [[Kelimpahan unsur|urutan ke-24 dalam kelimpahan universal dan ke-13 dalam kelimpahan terestrial]]. [[Fluorit]], sumber mineral utama fluorin yang memberi nama unsur tersebut, pertama kali dijelaskan pada tahun 1529; karena ia ditambahkan ke pada [[bijih]] logam untuk menurunkan titik leburnya agar dapat mempermudah [[Peleburan (metalurgi)|peleburan]], kata kerja Latin ''fluo'' yang berarti 'mengalir' memberi nama mineral tersebut. Diusulkan sebagai unsur pada tahun 1810, fluorin terbukti sulit dan berbahaya untuk dipisahkan dari senyawanya, dan beberapa peneliti awal meninggal atau menderita luka akibat percobaan mereka. Baru pada tahun 1886 ahli kimia Prancis [[Henri Moissan]] mengisolasi fluorin unsur menggunakan [[elektrolisis]] suhu rendah, sebuah proses yang masih digunakan untuk produksi modern. Produksi industri gas fluorin untuk [[Pengayaan uranium#Metode pengayaan|pengayaan uranium]], aplikasi terbesarnya, dimulai selama [[Proyek Manhattan]] dalam [[Perang Dunia II]].
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Pada tahun 1529, [[Georgius Agricola]] menggambarkan fluorit sebagai aditif yang digunakan untuk menurunkan titik lebur logam selama [[Peleburan (metalurgi)|peleburan]].{{sfn|Greenwood|Earnshaw|1998|p=790}}<ref name="assassinated">{{harvnb|Senning|2007|p=[https://books.google.com/?id=Fl4sdCYrq3cC&pg=PA149 149]}}.</ref>{{refn|[[Basilius Valentinus]] diduga menggambarkan fluorit pada akhir abad ke-15, tetapi karena tulisannya ditemukan 200 tahun kemudian, kebenaran daripada karya ini diragukan.<ref name="PopSci">{{Harvnb|Stillman|1912}}.</ref><ref>{{harvnb|Principe|2012|pp=140, 145}}.</ref><ref>{{Harvnb|Agricola|Hoover|Hoover|1912|loc=catatan kaki dan komentar, hlm. xxx, 38, 409, 430, 461, 608}}.</ref>||group="note"}} Dia menulis kata Latin ''fluorēs'' (''fluor,'' alir) untuk batuan fluorit. Nama tersebut kemudian berkembang menjadi ''fluorspar'' (masih umum digunakan) dan kemudian ''fluorit''.<ref name="KGS fluorite terminology">{{harvnb|Norwood|Fohs|1907|p=[https://archive.org/stream/bulletin01kentgoog#page/n94/mode/2up 52]}}.</ref>{{sfn|Greenwood|Earnshaw|1998|p=109}}<ref>{{Harvnb|Agricola|Hoover|Hoover|1912|loc=kata pengantar, hlm. [https://archive.org/stream/georgiusagricola00agririch#page/380/mode/2up 380–381]}}.</ref> Komposisi fluorit kemudian ditentukan sebagai [[Kalsium fluorida|kalsium difluorida]].<ref name="Weeks">{{harvnb|Weeks|1932}}.</ref>
[[Asam fluorida]] digunakan dalam [[etsa kaca]] dari tahun 1720 dan seterusnya.{{refn|Atau mungkin sejak tahun 1670 dan seterusnya; Partington<ref name="Partington">{{harvnb|Partington|1923}}.</ref> dan Weeks<ref name="Weeks" /> memberikan penjelasan yang berbeda.||group="note"}} [[Andreas Sigismund Marggraf]] pertama kali mengkarakterisasinya pada tahun 1764 ketika dia memanaskan fluorit dengan asam sulfat, dan larutan yang dihasilkan merusak wadah kacanya.<ref>{{harvnb|Marggraf|1770}}.</ref><ref name="ModFcchem" /> Kimiawan Swedia [[Carl Wilhelm Scheele]] mengulangi percobaan pada tahun 1771, dan menamakan produk asamnya sebagai ''fluss-spats-syran'' (asam fluorspar).<ref name="ModFcchem" /><ref>{{harvnb|Scheele|1771}}.</ref> Pada tahun 1810, fisikawan Prancis [[André-Marie Ampère]] memperkirakan bahwa hidrogen dan unsur yang analog dengan klorin merupakan asam fluorida.<ref>{{harvnb|Ampère|1816}}.</ref> Dia juga mengusulkan dalam sebuah surat kepada [[Humphry Davy]] tertanggal 26 Agustus 1812 bahwa zat yang saat itu tidak diketahui ini dapat diberi nama ''fluorin'' dari asam fluorat dan akhiran ''-in'' dari halogen lainnya.<ref>{{Cite book|url = https://books.google.com/books?id=kslaDwAAQBAJ&pg=PA3|title = Fluorine: A Paradoxical Element|isbn = 9780128129913|last1 = Tressaud|first1 = Alain|date = 6 October 2018|access-date = 2022-08-04|archive-date = 2023-07-22|archive-url = https://web.archive.org/web/20230722094701/https://books.google.com/books?id=kslaDwAAQBAJ&pg=PA3|dead-url = no}}</ref>{{sfn|Davy|1813|p=[https://books.google.com/books?id=dhdGAAAAMAAJ&pg=PA278 278]}} Kata ini, seringkali dengan modifikasi, digunakan di sebagian besar bahasa Eropa; namun, bahasa Yunani, Rusia, dan beberapa lainnya, mengikuti saran Ampère berikutnya, menggunakan nama ''ftor'' atau turunannya, dari bahasa Yunani φθόριος (''phthorios'', destruktif).{{sfn|Banks|1986|p=11}} Nama Latin Baru ''fluorum'' memberikan unsur tersebut dengan lambangnya saat ini, '''F'''; Fl digunakan dalam beberapa makalah awal.<ref name="dissolve" />{{refn|Fl, sejak 2012, digunakan untuk [[flerovium]].||group="note"}}
===Isolasi===
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:CaF<sub>2</sub> + H<sub>2</sub>SO<sub>4</sub> → 2 HF(g) + CaSO<sub>4</sub>
Gas HF kemudian dapat diserap dalam air atau dicairkan.<ref>{{cite book |last1=Norris Shreve |last2=Joseph Brink, Jr. |title=Chemical Process Industries |url=https://archive.org/details/chemicalprocessi0000shre_s8m7 |date=1977 |isbn=0070571457 |page=[https://archive.org/details/chemicalprocessi0000shre_s8m7/page/321 321] |edition=4}}</ref>
Sekitar 20% HF yang diproduksi adalah produk sampingan dari produksi pupuk, yang menghasilkan [[asam heksafluorosilikat]] (H<sub>2</sub>SiF<sub>6</sub>), yang dapat didegradasi untuk melepaskan HF secara termal dan hidrolisis:
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