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<section begin=R32 />
{{TwoLegStart}}
{{TwoLegResult|'''[[Wolverhampton Wanderers F.C.|Wolverhampton Wanderers]]'''|ENG|16–3|[[RCD Espanyol|Espanyol]]|ESP|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Wolverhampton 1.1|{{small|20Wanderers Feb}}v Espanyol|4–0]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Espanyol 1.2|{{small|27v Feb}}Wolverhampton Wanderers|2–3]]}}
{{TwoLegResult|[[Sporting CP]]|POR|24–5|'''[[İstanbul Başakşehir F.K.|İstanbul Başakşehir]]'''|TUR|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Sporting 2.1|{{small|20CP Feb}}v İstanbul Başakşehir|3–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32İstanbul 2.2Başakşehir v Sporting CP|1–4]] {{small|27 Febaet}}]]}}
{{TwoLegResult|'''[[Getafe CF|Getafe]]'''|ESP|33–2|[[AFC Ajax|Ajax]]|NED|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Getafe 3.1|{{small|20v Feb}}Ajax|2–0]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Ajax 3.2|{{small|27v Feb}}Getafe|1–2]]}}
{{TwoLegResult|'''[[Bayer 04 Leverkusen|Bayer Leverkusen]]'''|GER|45–2|[[FC Porto|Porto]]|POR|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Bayer 4.1|{{small|20Leverkusen Feb}}v Porto|2–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Porto 4.2|{{small|27v Feb}}Bayer Leverkusen|3–1]]}}
{{TwoLegResult|'''[[F.C. Copenhagen|Copenhagen]]'''|DEN|54–2|[[Celtic F.C.|Celtic]]|SCO|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Copenhagen 5.1|{{small|20v Feb}}Celtic|1–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Celtic 5.2|{{small|27v Feb}}Copenhagen|3–1]]}}
{{TwoLegResult|[[APOEL FC|APOEL]]|CYP|60–4|'''[[FC Basel|Basel]]'''|SUI|[[Babak gugur Liga Eropa UEFA 2019–2020#R32APOEL 6.1|{{small|20v Feb}}Basel|0–3]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Basel 6.2v APOEL|{{small|27 Feb}}0–1]]}}
{{TwoLegResult|[[CFR Cluj]]|ROU|71–1 ([[Away goals rule|a]])|'''[[Sevilla FC|Sevilla]]'''|ESP|[[Babak gugur Liga Eropa UEFA 2019–2020#R32CFR 7.1|{{small|20Cluj Feb}}v Sevilla|1–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Sevilla 7.2|{{small|27v Feb}}CFR Cluj|0–0]]}}
{{TwoLegResult|'''[[OlympiacosOlympiakos F.C.|OlympiacosOlympiakos]]'''|GRE|82–2 ([[Away goals rule|a]])|[[Arsenal F.C.|Arsenal]]|ENG|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Olympiakos 8.1|{{smallv Arsenal|20 Feb}}0–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Arsenal 8.2v Olympiakos|2–1]] {{small|27 Febaet}}]]}}
{{TwoLegResult|[[AZ Alkmaar|AZ]]|NED|91–3|'''[[LASK]]'''|AUT|[[Babak gugur Liga Eropa UEFA 2019–2020#R32AZ 9.1|{{small|20v Feb}}LASK|1–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32LASK 9.2v AZ|{{small|27 Feb}}0–2]]}}
{{TwoLegResult|[[Club Brugge KV|Club Brugge]]|BEL|101–6|'''[[Manchester United F.C.|Manchester United]]'''|ENG|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Club 10.1|{{small|20Brugge Feb}}v Manchester United|1–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Manchester 10.2|{{small|27United Feb}}v Club Brugge|0–5]]}}
{{TwoLegResult|[[PFC Ludogorets Razgrad|Ludogorets Razgrad]]|BUL|111–4|'''[[Inter Milan]]'''|ITA|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Ludogorets 11.1|{{small|20Razgrad Feb}}v Internazionale|0–2]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Internazionale 11.2|{{small|27v Feb}}Ludogorets Razgrad|1–2]]}}
{{TwoLegResult|'''[[Eintracht Frankfurt]]'''|GER|126–3|[[FC Red Bull Salzburg|Red Bull Salzburg]]|AUT|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Eintracht 12.1|{{small|20Frankfurt Feb}}v Red Bull Salzburg|4–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Red 12.2|{{small|27Bull Feb}}Salzburg v Eintracht Frankfurt|2–2]]}}
{{TwoLegResult|'''[[FC Shakhtar Donetsk|Shakhtar Donetsk]]'''|UKR|135–4|[[S.L. Benfica|Benfica]]|POR|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Shakhtar 13.1|{{small|20Donetsk Feb}}v Benfica|2–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Benfica 13.2|{{small|27v Feb}}Shakhtar Donetsk|3–3]]}}
{{TwoLegResult|'''[[VfL Wolfsburg|Wolfsburg]]'''|GER|145–1|[[Malmö FF]]|SWE|[[Babak gugur Liga Eropa UEFA 2019–2020#R32VfL 14.1|{{small|20Wolfsburg Feb}}v Malmö FF|2–1]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Malmö 14.2|{{small|27FF Feb}}v VfL Wolfsburg|3–0]]}}
{{TwoLegResult|'''[[A.S. Roma|Roma]]'''|ITA|152–1|[[K.A.A. Gent|Gent]]|BEL|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Roma 15.1|{{small|20v Feb}}Gent|1–0]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Gent 15.2|{{small|27v Feb}}Roma|1–1]]}}
{{TwoLegResult|'''[[Rangers F.C.|Rangers]]'''|SCO|164–2|[[S.C. Braga|Braga]]|POR|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Rangers 16.1|{{small|20v Feb}}Braga|3–2]]|[[Babak gugur Liga Eropa UEFA 2019–2020#R32Braga 16.2|{{small|26v Feb}}Rangers|1–0]]}}
|}<section end=R32 />
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