Oronitrat adalah sebuah oksoanion tetrahedral dari nitrogen dengan rumus NO3−4. Ia pertama kali diidentifikasi pada 1977[1] and is currently known in only two compounds, sodium orthonitrate (Na3NO4) and potassium orthonitrate (K3NO4). These can be prepared by fusion of the nitrate and metal oxide under high temperatures[2] and ideally high pressures (several GPa).[3]

Ortonitrat
Nama
Nama IUPAC
Orthonitrate
Penanda
Model 3D (JSmol)
3DMet {{{3DMet}}}
Nomor EC
Nomor RTECS {{{value}}}
  • InChI=1S/NO4/c2-1(3,4)5/q-3
    Key: QKSQKFHZSYXUGK-UHFFFAOYSA-N
  • [N+]([O-])([O-])([O-])[O-]
Sifat
NO3−4
Massa molar 78.006
Kecuali dinyatakan lain, data di atas berlaku pada suhu dan tekanan standar (25 °C [77 °F], 100 kPa).
Referensi

Referensi

  1. ^ Jansen, Martin (August 1977). "Detection of an Orthonitrate by Vibrational Spectroscopy: Na3NO4". Angewandte Chemie International Edition in English. 16 (8): 534–535. doi:10.1002/anie.197705341. 
  2. ^ Jansen, Martin (1979-08-31). "Crystal Structure of Na3NO4". Angewandte Chemie International Edition in English. 18 (9): 698–699. doi:10.1002/anie.197906982. 
  3. ^ Quesada Cabrera, R.; Sella, A.; Bailey, E.; Leynaud, O.; McMillan, P.F. (April 2011). "High-pressure synthesis and structural behavior of sodium orthonitrate Na3NO4". Journal of Solid State Chemistry. 184 (4): 915–920. doi:10.1016/j.jssc.2011.02.013.